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Study of new tellurite glasses in the TeO2-ZnO-La2O3 (TZL) system for the manufacturing of mid-infrared multimaterial optical fibers and specialty op…

2023

This thesis work was carried out using tellurite glasses from the TeO2-ZnO-La2O3 (TZL) ternary diagram for optical fibers manufacturing. The choice to use this system is motivated by the ambition to improve the transmission of optical signals within oxide glasses for which absorption bands related to OH groups are present in the transparency window. A structural study is first carried out on these glasses by Raman spectroscopy in order to understand the influence of the composition on physicochemical properties (especially on optical and thermal properties) but also to estimate the ability of a vitreous matrix to reorganize when subjected to a thermal solicitation such as the preform-to-fib…